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I am looking into silicon solar cells but cannot find any sources which explain why open circuit voltage decreases with rise in temperature.
I know that voltage decreases with temperature but why?
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By the Shockley diode equation, the current diverted through the diode is:
where I0 = reverse saturation current n = diode ideality factor q = elementary charge k = Boltzmann’s constant T = absolute temperature Temperature affects the characteristic equation in two ways: directly, via T in the exponential term, and indirectly via its effect on I0. The net effect is to reduce VOC linearly with increasing temperature. The magnitude of this reduction is inversely proportional to VOC; that is, cells with higher values of VOC suffer smaller reductions in voltage with increasing temperature.